期刊
CHEMICAL ENGINEERING & TECHNOLOGY
卷 33, 期 11, 页码 1888-1892出版社
WILEY-BLACKWELL
DOI: 10.1002/ceat.201000251
关键词
Emulsion polymerization; Microwave-activated polymerization; Microwave-assisted syntheses; Simulation
资金
- Consejo Nacional de Ciencia y Tecnologia (CONACYT) [101682]
- Universidad Nacional Autonoma de Mexico, Direccion General de Asuntos del Personal Academico (DGAPA-UNAM) [IN119510]
The emulsion polymerization of styrene, activated by microwave irradiation and conductive heating, was modeled using the EMULPOLY (R) simulation package of the University of Waterloo. Microwave-activated initiation was modeled as adding a hypothetical second initiator. The kinetic rate constants and model parameters used in the simulation were taken from the simulator database, with the exception of the microwave activation constant, k(ir), and the efficiency, f(r), of the hypothetical initiator. Model predictions of conversion, number- and weight-average molecular weights, for microwave- and thermally activated systems agreed well with the experimental data reported in the literature. The effects of microwave power supplied to the system on monomer conversion, molecular weight values and particle number were analyzed.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据