期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 81, 页码 11399-11402出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc05290e
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资金
- French National Agency (ANR) [ANR-14-CE07-0012-02]
- Technion Russell Berrie Institute of Nanotechnology (RBNI)
- SERB, Govt. of India [SB/S2/RJN-113/2016]
An original degradable fluorinated surfactant, 3-hydroxy-2-(trifluoromethyl)propanoic acid (MAF-OH), was applied for the emulsion polymerization of vinylidene fluoride (VDF) to yield a latex of PVDF, consisting of typically 100 nm particle diameters. This surfactant was shown to be easily decomposed in subcritical water, releasing fluoride anions. The % reversed head-to head (H-H) addition is greatly minimized (2.4%) in the PVDF, prepared in the presence of MAF-OH surfactant.
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