4.7 Article

A water-stable homochiral luminescent MOF constructed from an achiral acylamide-containing dicarboxylate ligand for enantioselective sensing of penicillamine

期刊

CHEMICAL COMMUNICATIONS
卷 54, 期 77, 页码 10901-10904

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06274a

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  1. National Natural Science Foundation of China [21771096, 21001061]
  2. Natural Science Foundation of Shandong Province [ZR2014BQ034]

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A water-stable homochiral luminescent metal-organic framework (HLMOF), {[Cd(l)(4,4-bipy)]DMA5H(2)O}(n) (1), was obtained by a spontaneous symmetry-breaking crystallization from achiral precursors without any enantiopure auxiliary. The homochirality of 1 was confirmed by single-crystal X-ray diffraction and CD spectroscopy. Complex 1 exhibits an interesting enantioselective sensing of d/l-penicillamine in water.

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