期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 68, 页码 9418-9421出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04362k
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Dioxygen adsorbs in the end-on configuration on-top of the Fe atoms of an iron phthalocyanine monolayer supported on Ag(100) and is partly cleaved at room temperature to produce O/FePc/Ag(100). Scanning tunnelling microscopy coupled to density functional theory calculations gives the first experimental evidence of the substrate involvement in the O-2 bond dissociation.
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