期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 67, 页码 9301-9304出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc05233f
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资金
- Deutsche Forschungsgemeinschaft [GRK 1582]
The synthesis and structural characterisation of the difluorido organo gold(III) complexes [AuClF2(SIMes)] and [AuF2(OTeF5)(SIMes)] are presented. The substitution of a fluorido ligand in [AuF3(SIMes)] by an OTeF5 group increases the Lewis acidity of the Au moiety. A scale for carbene affinities is presented, which correlates calculated and experimental values for the Lewis acidity of the metal centre in akin compounds.
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