期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 65, 页码 9063-9066出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04482a
关键词
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资金
- MINECO (Spain) [CTQ2016-75671-P, CTQ2017-84692-R]
- Ramon y Cajal Program
- Excellence Unit Maria de Maeztu'' [MDM-2015-0538]
- EU FEDER
- Ministero dell'Istruzione, dell'Universita e della Ricerca (Italy)
- MINECO
We report the application of a post-synthetic solid-state cation-exchange process to afford a novel 3D MOF with hydrated barium cations hosted at pores able to trigger selective and reversible SO2 adsorption. Computational modelling supports the full reversibility of the adsorption process on the basis of weak supramolecular interactions between SO2 and coordinated water molecules.
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