期刊
CHEMICAL COMMUNICATIONS
卷 54, 期 74, 页码 -出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc04932g
关键词
-
资金
- National Natural Science Foundation of China [21772119, 21620102003, 21302124]
- Shanghai Municipal Education Commission [201701070002E00030]
- Shanghai Chenguang Project [14CG11]
The last two decades have witnessed the development of metal-catalyzed asymmetric additions of arylboronic acids to electron-deficient double bonds. Much research has been directed towards Rh(i)-catalysis because of the high activity of this transition metal for these types of reactions. Recently, significant advances have emerged in Pd(ii), Ni(ii), and Co(ii)-catalyzed asymmetric additions of organoboron reagents. This feature article highlights the development of additions to ketimines catalyzed by these three metals, that is, (i) Pd(ii)-catalyzed enantioselective additions of arylboronic acids to ketimines, (ii) Ni(ii)-catalyzed enantioselective additions of arylboronic and alkenylboronic acids to ketimines, and (iii) Co(ii)-catalyzed enantioselective additions of potassium allyltrifluoroborate to ketimines.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据