期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 2, 页码 162-164出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45134h
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资金
- Welch Foundation [AI-0045]
- NSF [CHE-0821254, CHE-0946998]
- Research Corporation for Science Advancements [20092]
- Texas State University
- NSF REU program [CHE-1156579]
Treatment of dichlorophenylphosphine with two equivalents of carbonyl-decorated carbenes results in a two-electron reduction of the phosphorus centre concomitant with carbene oxidation to afford novel phosphaalkenes as confirmed via crystallographic, spectroscopic, and DFT analyses.
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