期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 92, 页码 14360-14363出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06188h
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资金
- MEXT, Japan
- JST
- JSPS
Direct carboxylation of simple arenes under atmospheric pressure of CO2 is achieved through a rhodium-catalyzed C-H bond activation without the assistance of a directing group. Various arenes such as benzene, toluene, xylene, electron-rich or electron-deficient benzene derivatives, and heteroaromatics are directly carboxylated with high TONs.
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