期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 37, 页码 4776-4787出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00738g
关键词
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资金
- JSPS KAKENHI [25708022, 23655210, 19750110, 21750140]
- Grants-in-Aid for Scientific Research [25708022, 21750140, 19750110, 23655210] Funding Source: KAKEN
Pillar[n]arenes, which we first synthesized and named in 2008, are new pillar-shaped macrocyclic hosts. Pillar[n] arene homologues with n = 5-10 have already been synthesized, but the cyclic pentamers, i.e., pillar[5] arenes, and cyclic hexamers, i.e., pillar[6] arenes, have been most widely used because these can be obtained in good yields. To date, nearly all pillar[n] arene-based supramolecular assemblies have been constructed using pillar[5]- and pillar[6] arene scaffolds. In this feature article, we describe supramolecular assemblies built using host-guest interactions depending on the cavity sizes of pillar[5]- and pillar[6] arenes. We first discuss the effects of the type of substituents on the rims of pillar[5]- and pillar[6] arenes on their solubilities, functionalities and host-guest properties. We then discuss supramolecular assemblies based on their host-guest properties and pillar-shaped architectures.
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