期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 83, 页码 12450-12453出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04401k
关键词
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资金
- NCN [NN 209 75 83 40]
- ANR GALAC project [ANR-10-CD2I-011]
While Ru is a poor hydrogenation catalyst compared to Pt or Pd in the gas phase, it is efficient under aqueous phase conditions in the hydrogenation of ketones such as the conversion of levulinic acid into gamma-valerolactone. Combining DFT calculations and experiments, we demonstrate that water is responsible for the enhanced reactivity of Ru under those conditions.
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