期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 91, 页码 14157-14160出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07062c
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资金
- National Natural Science Foundation of China [21272036, 21332010]
- National Basic Research Program of China [2012CB21600]
A general method to form a C(SP3)-SCF3 bond via copper-mediated oxidative trifluoromethylthiolation of unactivated alkenes with stable nucleophilic AgSCF3 was developed. This protocol provides a direct and efficient access to a series of trifluoromethylthiolated allylic compounds with broad functional group tolerance.
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