4.7 Article

Highly active phosphite gold(I) catalysts for intramolecular hydroalkoxylation, enyne cyclization and furanyne cyclization

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 38, 页码 4937-4940

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00839a

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资金

  1. DAAD
  2. Investigador FCT program
  3. FCT-Portugal
  4. QREN/FEDER (COMPETE - Programa Operacional Fatores de Competitividade) [PTDC/QUI-QUI/112913/2009]

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New and highly active mononuclear phosphite gold(I) catalysts are described. Turn-over numbers up to 37 000 for the furan-yne reaction and up to 28 000 000 for the two-fold hydroalkoxylation of alkynes are reported.

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