期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 42, 页码 5572-5575出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01058b
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资金
- NRF of Korea through CRI [2-2012-1794-001-1]
- GRL [2013-4213-001-1]
- Basic Science Research Program [2013R1A1A2062737]
- National Research Foundation of Korea [2010-00353, 2013R1A1A2062737, 2012R1A3A2048842] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Hydroxylation of alkanes by a mononuclear nonheme iron(V)-oxo complex, [Fe(V)(O)(TAML)](-), is initiated by a rate-determining hydrogen atom(H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.
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