期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 76, 页码 11211-11213出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04481a
关键词
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资金
- Core Research for Evolutional Science and Technology (CREST) program of the Japan Science and Technology Agency (JST)
- MEXT, Japan [25810062]
- JSPS
- Grants-in-Aid for Scientific Research [14J04940, 25810062] Funding Source: KAKEN
Addition of catalytic amounts of zinc salts facilitated the hydrogenation of amides catalyzed by a ruthenium complex bearing 2-(diphenylphosphino) ethanamine (L1). The combined catalytic system of the ruthenium complex [RuCl2(L-1)(2)] with a zinc salt such as Zn(OCOCF3)(2) mediated hydrogenation of various amides under mild conditions to afford the corresponding primary alcohols.
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