期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 71, 页码 10291-10294出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04911j
关键词
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资金
- Izumi Science and Technology foundation
- Murata Science Foundation
- Japan Science Society
- Asahi Glass Foundation
An oxidative skeletal rearrangement of 1,1'-binaphthalene-2,2'-diamines (BINAMs) that involves the cleavage of a strong C-C single bond of the binaphthalene unit and the nitrogen migration has been discovered. The unprecedented rearrangement enables access to a series of U-shaped azaacenes otherwise difficult to prepare in a selective manner by classical methods. Moreover, physicochemical properties of the unique azaacenes have been comprehensively investigated.
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