期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 91, 页码 14101-14104出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06328g
关键词
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资金
- 973 Program [2011CB80860, 2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
A new radical oxytrifluoromethylation of alkenes via an aerobic C-vinyl-heteroatom bond oxygenation process is reported, in which O-2 and a catalytic amount of K2S2O8 work in concert to activate CF3SO2Na. Mechanistic investigation disclosed that CF3SO2 center dot could react with O-2 to reinitiate radical chain process.
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