期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 94, 页码 14805-14808出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06992g
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资金
- Centre National de la Recherche Scientifique (CNRS)
- Universite Paul Sabatier (UPS)
- Deutsche Forschungsgemeinschaft, the European Union (Marie Curie ITN SusPhos) [317404]
- Council for Chemical Sciences of the Netherlands Organization for Scientific Research (NWO/CW)
- PHC Van Gogh program [31616SK]
Coordination of Mes(2)PC(=CHPh)AltBu(2) to metal chlorides has been studied. Bridging P -> M-Cl -> Al coordinations were observed with Rh and Pd fragments, while chloride abstraction systematically occurred with gold. The resulting zwitterionic complexes have been fully characterized and analyzed by DFT calculations.
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