期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 13, 页码 1533-1536出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48914k
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资金
- MINECO [CTQ2010-16088/BQU, CTQ2011-27033]
- AGAUR [2009SGR47, 2009SGR0259]
- European Research Council [321066]
- ICIQ Foundation
The oxidative addition of C-sp2-Br or C-sp2-I bonds to gold( I) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold( III) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish.
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