期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 33, 页码 4319-4321出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00773e
关键词
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资金
- Fonds der Chemischen Industrie
Two P-2-phosphazenyl groups were linked via a C-2-symmetric binaphthyl backbone resulting in two novel chiral superbases with dimethylamino and pyrrolidino substituents. We investigated their basic properties and coordination chemistry towards a cationic alkyl aluminum fragment. The outstanding basicity of the chiral tetrasphosphazenes presented herein leads to interesting perspectives for application in asymmetric Bronsted base catalysis.
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