期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 16, 页码 2058-2060出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48670b
关键词
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资金
- State Key Project of Fundamental Research for Nanoscience and Nanotechnology [2011CB932401, 2011CBA00500]
- National key Basic Research Program of China [2012CB224802]
- Ministry of Science and Technology of China [2012CB722605]
- National Natural Science Foundation of China [21221062, 21172128, 21171105, 21322107, 21131004]
- China Postdoctoral Science Foundation [2012M520241, 2012M520010, 2013T60097]
Regioselective hydroboration of terminal and internal alkynes is realized by using 10 mol% copper powder (0.3-1 mu m) at room temperature. 24 alkynes were efficiently converted into vinylboronates in up to 96% yield without addition of any ligand or additive.
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