期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 57, 页码 7642-7645出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02114b
关键词
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资金
- Natural Science Foundation of China [21172162, 21372174]
- Young National Natural Science Foundation of China [21202113]
- Ph.D. Programs Foundation of Ministry of Education of China [2013201130004]
- Key Laboratory of Organic Synthesis of Jiangsu Province [KJS1211]
- PAPD
- Soochow University
A novel radical phosphinylation of alpha,alpha-diaryl allylic alcohols with arylphosphine oxides was described for the direct preparation of alpha-aryl-beta-phosphinylated carbonyl ketones in medium to good yields via 1,2-aryl migration. In this reaction, formation of new C(Ar)-C(sp(3)) and C(sp(3))-P bonds was observed.
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