期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 97, 页码 15404-15406出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07527g
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资金
- Danish Council of Strategic Research in the framework of the DSF proposal Nanoparticle synthesis for catalysis''
Flame spray pyrolysis (FSP) of Bi(III)-and Mo(VI)-2-ethylhexanoate dissolved in xylene resulted in various nanocrystalline bismuth molybdate phases depending on the Bi/Mo ratio. Besides alpha-Bi2Mo3O12 and gamma-Bi2MoO6, FSP gave direct access to the metastable beta-Bi2Mo2O9 phase with high surface area (19 m(2) g(-1)). This phase is normally only obtained at high calcination temperatures (>560 degrees C) resulting in lower surface areas. The beta-phase was stable up to 400 degrees C and showed superior catalytic performance compared to alpha- and gamma-phases in selective oxidation of propylene to acrolein at temperatures relevant for industrial applications (360 degrees C).
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