4.7 Article

Synthesis of a guanidine NHC complex and its application in borylation reactions

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CHEMICAL COMMUNICATIONS
卷 50, 期 33, 页码 4344-4346

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00550c

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  1. Taiwan National Science Council [NSC: 101-2628-M-001-004-MY3]
  2. Academia Sinica

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Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were isolated and fully characterized. These Cu complexes are found to be versatile catalysts for hydroboration, semihydrogenation and carboboration of alkynes in a highly stereo- and regioselective fashion.

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