期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 92, 页码 14386-14389出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05661b
关键词
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资金
- 973 Program [2011CB80860, 2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
By using alkanes and mercaptans as the nucleophiles with di-tert-butyl peroxide (DTBP) as the oxidant, I-2-catalyzed oxidative C(sp(3))-H/S-H coupling was achieved. This protocol provides a novel process to construct C(sp(3))-S bonds from commercially available hydrocarbons and mercaptans.
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