期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 50, 页码 6574-6577出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49704f
关键词
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资金
- EPSRC [EP/H000925]
- EPSRC [EP/I038721/1, EP/K039687/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K039687/1, EP/I038721/1] Funding Source: researchfish
Introducing multiple reactive functional groups at the periphery of dendrimer materials presents considerable challenges if the functionality is able to self-react. An efficient and facile approach to introducing masked thiols at the surface of polyester dendrimers is presented. One-pot, deprotection/thiol-acrylate Michael addition from the xanthate-functional dendritic substrates (generation zero to two) has been achieved for the first time, with high efficiency demonstrated using three acrylates of varying chemistry and avoiding disulfide formation.
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