期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 12, 页码 1408-1410出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47830k
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资金
- European Union (the Erasmus Mundus program)
A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.
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