4.7 Article

Confinement stabilises single crystal vaterite rods

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 36, 页码 4729-4732

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01093k

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资金

  1. EPSRC [EP/I001514/1, EP/H005374/1]
  2. Engineering and Physical Sciences Research Council [EP/K039202/1, EP/I001514/1, EP/H005374/1] Funding Source: researchfish
  3. EPSRC [EP/K039202/1] Funding Source: UKRI

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Single-crystals of vaterite, the least-stable anhydrous polymorph of CaCO3, are rare in biogenic and synthetic systems. We here describe the synthesis of high aspect ratio single crystal vaterite rods under additive-free conditions by precipitating CaCO3 within the cylindrical pores of track-etch membranes.

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