期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 28, 页码 3668-3670出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00537f
关键词
-
资金
- Chinese Scholarship Council Graduate Fellowship
- Materials Science of Actinides, an Energy Frontier Research Center
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001089]
Th(VO3)(2)(SeO3) and Ln(VO3)(2)(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (Th-IV vs. Ln(III); Se(IV)O(3)(2-)vs. (IO3-)-O-V) are possible in this structure type.
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