期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 64, 页码 8978-8981出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03614j
关键词
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资金
- MINECO [CTQ2011-28942-CO2-01, CTQ2011-27033]
- Junta de Andalucia [P07-FQM-02745, P10-FQM-06292]
- MEC
Electron deficient azides are challenging substrates in CuAAC reactions. Particularly, when N-carbonyl azides are applied the formation of N-carbonyl triazoles has not yet been observed. We report herein the first example of this class of reaction, with a copper-based system that efficiently enables the synthesis of N-carbamoyl 1,2,3-triazoles by [3+2] cycloaddition of N-carbamoyl azides and alkynes.
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