期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 85, 页码 12836-12839出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04228j
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资金
- MEXT/JSPS [24550165, 25220802, 24655029, 21245011]
- Strategic Research Foundation at Private Universities
- Mitsubishi Chemical Corporation Fund
- Sumitomo Foundation
- Shorai Foundation for Science and Technology
- Kurata Memorial Hitachi Science and Technology Foundation
- Tokuyama Science Foundation
- KDDI Foundation
- Grants-in-Aid for Scientific Research [24550165, 24655029, 23350018] Funding Source: KAKEN
Tethering four 1- versus 2-naphthyls to the same chiral scaffold derived from tartaric acid led to oppositely signed circularly polarized luminescence (CPL) and circular dichroism (CD) in solution, which not only reveals the decisive role of the spatial arrangement of chromophores/fluorophores in determining the chiroptical behaviors but also provides us with a versatile tool for switching the signs of CPL and CD without using the antipodal scaffold.
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