期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 47, 页码 6281-6284出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03124e
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资金
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft
- Humboldt Foundation
- Cluster of Excellence RESOLV - DFG [EXC 1069]
Using a prototypical Diels-Alder reaction as benchmark, we show that dicationic halogen-bond donors are capable of activating a neutral organic substrate. By various comparison experiments, the action of traces of acid or of other structural features of the halogen-bond donor not related to halogen bonding are excluded with high certainty.
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