期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 69, 页码 9883-9886出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02499k
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资金
- Natural Sciences and Engineering Research Council (NSERC)
- Canada Foundation for Innovation
- Queen's University
Dimeric rhodium N-heterocyclic carbene complexes are demonstrated to be effective catalyst precursors for directed C-H borylation reactions at room temperature. The reactions are highly selective for mono-borylation and can be combined with a one-pot Suzuki-Miyaura coupling to give C-H arylation products with exclusive selectivity for mono-arylation without the requirement for steric blocking groups.
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