期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 95, 页码 15082-15085出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07478e
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资金
- EPSRC
- Engineering and Physical Sciences Research Council [1091989] Funding Source: researchfish
It has been shown that CyMe4-BTPhen-functionalized silica-coated maghemite (gamma-Fe2O3) magnetic nanoparticles (MNPs) are capable of quantitative separation of Am(III) from Eu(III) from HNO3 solutions. These MNPs also show a small but significant selectivity for Am(III) over Cm(III) with a separation factor of around 2 in 4 M HNO3. The water molecule in the cavity of the BTPhen may also play an important part in the selectivity.
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