期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 94, 页码 14756-14759出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07268e
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资金
- US National Science Foundation [CHE-1110911, CHE-1404911]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1404911] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1110911] Funding Source: National Science Foundation
We report the synthesis of lcucurbit[6]uril-cucurbit[7]uril heterodimer (1) by click chemistry of monofunctionalized CB[6] and CB[7] derivatives. Combinations of 1 with hydrophobic guest 4b or hydrophilic polymeric guests 5b and 5c deliver hydrophobic or amphiphilic supramolecular block copolymers which form supramolecular networks (6) and supramolecular micelles (7), respectively, in the solid state.
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