期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 85, 页码 12896-12898出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05684a
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资金
- CSIR, New Delhi
- UGC, New Delhi
- CSIR-Network project (CSIR-CDRI-THUNDER) [BSC0102]
We report a substituent controlled nucleophilic displacement of alkyl bromides with Bestmann-Ohira reagent yielding either dimethyl diazoalkylphosphonates or (E)-vinylphosphonates. The dimethyl diazoalkylphosphonates could be readily converted into corresponding (E)-vinylphosphonates in the presence of Cu following nitrogen elimination in quantitative yields.
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