期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 64, 页码 8871-8874出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04047c
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资金
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan
A catalytic method has been developed for construction of indoline-2-thiones containing an all-carbon quaternary centre at the C-3 position. Successive treatment of alpha,beta-unsaturated aldehydes bearing an isothiocyanato moiety with an in situ generated N-heterocyclic carbene and an appropriate heteroatomic nucleophile provided the 3,3-disubstituted indoline derivatives in moderate to good yields.
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