期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 41, 页码 5462-5464出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01431f
关键词
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资金
- BBSRC [120315]
- European Research Council under the European Union's Seventh Framework Programme [FP7/2007-2013]
- ERC [258775]
- European Research Council (ERC) [258775] Funding Source: European Research Council (ERC)
We report on a supramolecular self-assembly system that displays coupled light switching, biocatalytic condensation/hydrolysis and gelation. The equilibrium state of this system can be regulated by light, favouring in situ formation, by protease catalysed peptide synthesis, of self-assembling trans-Azo-YF-NH2 in ambient light; however, irradiation with UV light gives rise to the cis-isomer, which readily hydrolyzes to its amino acid derivatives (cis-Azo-Y + F-NH2) with consequent gel dissolution.
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