期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 6, 页码 645-648出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47632d
关键词
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资金
- DOE [DE-FG02-06ER15799, DE-FG02-03ER15455]
- NSF
- NATIONAL INSTITUTE OF ENVIRONMENTAL HEALTH SCIENCES [F32ES017390] Funding Source: NIH RePORTER
Mechanistic studies of H2O2 activation by complexes related to [(BPMEN)Fe-II(CH3CN)(2)](2+) with electron-rich pyridines revealed that a new intermediate formed in the presence of acetic acid with a 465 nm visible band can be associated with an unusual g = 2.7 EPR signal. We postulate that this chromophore is an acylperoxoiron(III) intermediate.
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