期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 57, 页码 7716-7719出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02962c
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资金
- Saudi Basic Industries Corporation (SABIC)
Preparing evenly-dispersed small size nickel nanoparticles over inert oxides remains a challenge today. In this context, a versatile method to prepare supported small size nickel nanoparticles (ca. 1-3 nm) with narrow size distribution via a surface organometallic chemistry (SOMC) route is described. The grafted mono(eta(3)-allyl) nickel complexes RMONi(eta(3)-C3H5) (M = Si or Al) as precursors are synthesized and fully characterized by elemental analysis, FTIR spectroscopy and paramagnetic solid-state NMR.
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