4.7 Article

C60 fullerenol as an active and stable catalyst for the synthesis of cyclic carbonates from CO2 and epoxides

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 71, 页码 10307-10310

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04891a

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资金

  1. National Natural Science Foundation of China [NSFC 21273244, 21333009, 21121063]
  2. Chinese Academy of Sciences [KJCX2-YW-N41]

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C-60 fullerenol was found to be a highly active, selective and stable catalyst for cycloaddition between CO2 and epoxides to produce various cyclic carbonates with excellent yields (89-99%). A solid/liquid interfacial hydrogen-bond assisted mechanism was proposed to account for its high efficiency.

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