4.7 Article

Zn-BTC MOFs with active metal sites synthesized via a structure-directing approach for highly efficient carbon conversion

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 20, 页码 2624-2627

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49187k

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资金

  1. 1000 Plan (Youth)
  2. 973 Program [2013CB834704]
  3. National Natural Science Foundation of China [21201018, 21231002, 21173021, 21276026]
  4. 111 Project [B07012]

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Three zinc-trimesic acid (Zn-BTC) MOFs, BIT-101, BIT-102 and BIT-103, have been synthesized via a structure-directing strategy. Interestingly, BIT-102 and -103 exhibit extraordinary catalytic performance (up to Conv. 100% and Sele. 95.2%) in the cycloaddition of CO2 under solvent-and halogen-free conditions without any additives or co-catalysts.

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