4.7 Article

Enantioselective synthesis of helical polydiacetylenes in the visible light region

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 18, 页码 2338-2340

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48478e

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资金

  1. National Natural Science Foundation of China [51173176, 51273186, 21074123, 91027024, 11374286, 61177053]
  2. Chinese Academy of Sciences [kjcx2-yw-m11]
  3. National Key Basic Research Program of China [2013CBA01703, 2012CB922003, 2012CB921900]
  4. Fundamental Research Funds for the Central Universities [WK2060200012]

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Herein, we demonstrate for the first time that the enantio-selective polymerization of DA monomers could be realized upon irradiation with circularly polarized visible light (CPVL), which could effectively provide chiral order in the propagating step of a polymerization reaction.

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