期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 26, 页码 3447-3449出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48913b
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资金
- Science Foundation Ireland [09/IN.1/I2635, 09/IN.1/B2650]
- Swedish Research Council
- European Union
- National Development Plan
- Science Foundation Ireland (SFI) [09/IN.1/B2650, 09/IN.1/I2635] Funding Source: Science Foundation Ireland (SFI)
A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis-(4-bromophenyl) porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions
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