期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 70, 页码 10144-10147出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02327g
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资金
- Laboratory Directed Research and Development at Lawrence Berkeley National Laboratory
- U. S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Chemical Sciences, Geosciences and Biosciences Division at Lawrence Berkeley National Laboratory [DE-AC02-05CH11231]
- ALS through Condensed Phase and Interfacial Molecular Science Program of DOE
- NSF [0416243]
- Office of the Secretary of Defense National Security Science and Engineering Faculty Fellowship
Spectroscopic evidence for an enhanced binding of Nitric Oxide (NO) to metal centers with lower oxidation states (open Cu1+ sites) in Cu-3(btc)(2) (HKUST-1) is presented. The Cu1+ sites created by thermal treatment or X-ray exposure exhibit a preferential adsorption of NO compared to H2O. This phenomenon demonstrates the potential use of MOFs with lower oxidation state metal centers for selective gas separation.
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