4.7 Article

Sodium superionic conduction in Na2B12H12

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 28, 页码 3750-3752

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49805k

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资金

  1. DOE EERE [DE-EE0002978, DE-AC04-94AL85000]
  2. Russian Foundation for Basic Research [12-03-00078]
  3. U.S. Civilian Research & Development Foundation (CRDF Global) [RUP1-7076-EK-12]
  4. National Science Foundation under Cooperative Agreement [OISE-9531011]
  5. Integrated Materials Research Center for the Low-Carbon Society (LC-IMR), Tohoku University
  6. Japan Science and Technology Agency (JST)
  7. JSPS KAKENHI [25220911]
  8. Grants-in-Aid for Scientific Research [26820311] Funding Source: KAKEN

向作者/读者索取更多资源

Impedance measurements indicate that Na2B12H12 exhibits dramatic Na+ conductivity (on the order of 0.1 S cm(-1)) above its order-disorder phase-transition at approximate to 529 K, rivaling that of current, solid-state, ceramic-based, Na-battery electrolytes. Superionicity may be aided by the large size, quasispherical shape, and high rotational mobility of the B12H122- anions.

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