期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 28, 页码 3750-3752出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49805k
关键词
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资金
- DOE EERE [DE-EE0002978, DE-AC04-94AL85000]
- Russian Foundation for Basic Research [12-03-00078]
- U.S. Civilian Research & Development Foundation (CRDF Global) [RUP1-7076-EK-12]
- National Science Foundation under Cooperative Agreement [OISE-9531011]
- Integrated Materials Research Center for the Low-Carbon Society (LC-IMR), Tohoku University
- Japan Science and Technology Agency (JST)
- JSPS KAKENHI [25220911]
- Grants-in-Aid for Scientific Research [26820311] Funding Source: KAKEN
Impedance measurements indicate that Na2B12H12 exhibits dramatic Na+ conductivity (on the order of 0.1 S cm(-1)) above its order-disorder phase-transition at approximate to 529 K, rivaling that of current, solid-state, ceramic-based, Na-battery electrolytes. Superionicity may be aided by the large size, quasispherical shape, and high rotational mobility of the B12H122- anions.
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