4.7 Article

Improved electrocatalytic activity for ethanol oxidation by Pd@N-doped carbon from biomass

期刊

CHEMICAL COMMUNICATIONS
卷 50, 期 84, 页码 12637-12640

出版社

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06206j

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资金

  1. National Natural Science Foundation of China [21376208, U1162124]
  2. Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China [LR13B030001]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [J20130060]
  4. Fundamental Research Funds for the Central Universities
  5. Program for Zhejiang Leading Team of ST Innovation
  6. Partner Group Program of the Zhejiang University
  7. Max-Planck Society

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Pd@N-doped carbon (Pd@CN) exhibited four and two times higher peak current density toward ethanol electrooxidation than Pd@active carbon and Pd@non-nitrogen carbon. Controlled experimental results indicated that the incorporation of nitrogen into the carbon matrix improved the percentage of Pd-o and increased the binding energy of Pd in Pd@CN, and accordingly enhanced the catalytic activity.

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