期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 92, 页码 14310-14313出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04925j
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资金
- Max-Planck-Society
- Arthur C. Cope foundation
Mutants of P450-BM3 evolved by directed evolution are excellent catalysts in the CH-activating oxidative hydroxylation of 1-tetralone derivatives and of indanone, with unusually high regio- and enantio-selectivity being observed. Similar results were achieved in the oxidative hydroxylation of tetralin and indane. The products are useful building blocks in the synthesis of a number of biologically active compounds.
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