期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 52, 页码 6846-6849出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49880h
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Centre for Self-Assembled Chemical Structure (CSACS)
- MIUR-FIRB (Nanosolar) project
- COST Perspect H2O
A rare example of dual coordination modes by a novel tridentate ligand gives rise to unique fac-and mer-Ru-(II/III) complexes. The mer-Ru-II-complex displays the farthest red-shift of a triplet metal-to-ligand charge transfer ((MLCT)-M-3) emission with a tridentate ligand for a mononuclear complex. This observation is a consequence of large bite angle and strong sigma-donation by the ligand, the combined effect of which helps to separate the energy of the (MLCT)-M-3 and (MC)-M-3 states.
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