期刊
CHEMICAL COMMUNICATIONS
卷 50, 期 42, 页码 5629-5632出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00607k
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资金
- Centre National de la Recherche Scientifique (CNRS)
- Universite de Strasbourg (UdS)
- Universite Joseph Fourier (UJF)
- Institut Universitaire de France (IUF)
- Agence Nationale de la Recherche (ANR) within the framework project in particular through a postdoctoral grant [ANR-08-JCJC-0113-01]
- Grants-in-Aid for Scientific Research [26708008] Funding Source: KAKEN
The reproducible formation of a 3D oxalate based coordination compound of formula (NH4)(5)[ (Mn2Cr3III)-Cr-II(ox)(9)]center dot 10H(2)O, with an unusual MnII/CrIII ratio, is presented. The original topology of the anionic network leads to antiferromagnetic long-range ordering whereas its guests favour high humidity-dependent proton conductivity.
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